How does the light through yonder window break? Seriously, Juliet, tell me. I have a test tomorrow!
Uncertain Principles: How Does Light Travel Through Glass?
It’s important to note that when [the quantum] picture is valid the probability of being absorbed then re-emitted by any individual atom is pretty tiny– when the light frequency is close to a resonance in the material, you would need to do something very different. (But then, if the light was close to a resonant frequency of the material, it wouldn’t be a transparent material…) while the probability of absorption and re-emission is tiny for any individual atom, though, there are vast numbers of atoms in a typical solid, so the odds are that the photon will be absorbed and re-emitted at some point during the passage through the glass are very good. Thus, on average, the photon will be delayed relative to one that passes through an equal length of vacuum, and that gives us the slowing effect that we see for light moving through glass.